Selective reduction of carboxylic acids to aldehydes through manganese catalysed hydrosilylation.
نویسندگان
چکیده
The direct reduction of carboxylic acids to disilylacetals was achieved through a manganese catalyzed hydrosilylation reaction in the presence of triethylsilane under mild conditions, at r.t. and under UV irradiation (350 nm). The aldehydes were obtained in good to excellent yields after acidic hydrolysis.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 85 شماره
صفحات -
تاریخ انتشار 2013